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Which of the following species, do not show disproportionation reaction and why? CIO , CIO2 , CIO3 and CIO4 Also write reactions for each of the species that disproportionates.

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The oxidation state of Cl in all the given species are:

Out of above species, CIO4 does not undergo disproportionation since in this oxoanion chlorine is already present in the highest oxidation state of +7 and hence cannot be further oxidized.

All the remaining oxoanions have oxidation state lower than the highest (i.e., +7) and higher than the lowest (i.e. -1) therefore, all these species undergo disproportionation reactions as shown below.

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