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Find the oxidation number of the atoms.

HClO3

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∴ i.e., (+1 × 1) + (x × 1) + (-2 × 3) = 0

⇒ 1 + x - 6 = 0

⇒ x = 6 - 1

⇒ x = +5

Oxidation number of Cl in HClO3 = +5

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