A first order reaction is given by :-
Ln(Ro/R) = Kt
where,
Ro - original amount of substance
R - amount of substance left
K - rate constant
and t - is the time elapsed.
Now,
Ro = 2R
which means,
2.303 log(2) = kt
\(\frac{0.693}{t}\) = rate constant
\(\frac{0.693}{20
}\) =0.03465 min-1
= 0.00575 sec-1