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Two samples A and B of same gas have same Initial pressure and volume. A undergoes an Isothermal expansion and B is subjected to adiabatic expansion. If the final volume in both cases is double the initial volume and work done In both the cases are same, then prove that 21-γ - 1 = In2, γ = \(\frac{c_p}{c_v}\).

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Let the initial pressure, pi = p1

initial volume, Vi = V1

final volume, Vf = V2

= 2V1

Work done in isothermal process,

Wiso = 2.303 RT log \((\frac{v_2}{v_1})\)

Since PV = RT (1 mol of gas),

Wiso = P1 V1 ln2 ......(1)

work done in adiabatic process,

For adiabatic process,

P1 \({V_1^γ}\) =P1 \(V_2^γ\) K (constant)

Since work done is same for both processes, Wiso = Wad

Re-arranging and simplifying (3),

21-γ - 1 = (1 - γ) ln2.

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