From the question we know that the block is in equilibrium
so when we resolve the angle the force F makes with the horizontal we get Fcos60 is the force that keeps the block in equilibrium against the 100N force ,so
100N=Fcos60
100N=F/2
Therefore F=200N
The normal force or normal reaction is again got got by resolving F
Nr=Fsin60(where Nr is the normal reaction)
Nr=200(√3)/2
Nr=100(√3)N