(i) 25° + 65° = 90° so, this is a complementary pair of angle.
(ii) 120° + 60° = 180° so, this is a supplementary pair of angle.
(iii) 63° + 27° = 90° so, this is a complementary pair of angle.
(iv) 100° + 80° = 180° so, this is a supplementary pair of angle.