Two adjacent angles are said to be linear pair of angles, if their non-common arms are two opposite rays.
Therefore linear pairs are listed below:
∠1 and ∠2
∠2 and ∠3
∠3 and ∠4
∠1 and ∠4
∠5 and ∠6
∠6 and ∠7
∠7 and ∠8
∠8 and ∠5
∠9 and ∠10
∠10 and ∠11
∠11 and ∠12
∠12 and ∠9
The two angles are said to be vertically opposite angles if the two intersecting lines have no common arms.
Therefore supplement of the angle are listed below:
∠1 and ∠3
∠4 and ∠2
∠5 and ∠7
∠6 and ∠8
∠9 and ∠11
∠10 and ∠12