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Explain electromeric effect, resonance effect and hyperconjugation.

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Electromeric effect is defined as the complete transfer of a shared pair of π-electrons to one of the atoms joined by a multiple bond on the demand of an attacking reagent. It is represented by E and the shifting of the electrons is shown by a curved arrow. 

The resonance effect is defined as ‘the polarity produced in the molecule by the interaction of two π-bonds or between a π-bond and lone pair of electrons present on an adjacent atom’. The effect is transmitted through the chain. 

Hyperconjugation involves delocalisation of σ electrons of C—H bond of an alkyl group directly attached to an atom of unsaturated system or to an atom with an unshared p orbital. The σ electrons of C—H bond of the alkyl group enter into partial conjugation with the attached unsaturated system or with the unshared p orbital. Hyperconjugation is a permanent effect.

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