1. SO2 is strongly irritating to the respiratory tract. SO2 at a concentration of 5 ppm causes throat and eyes irritation causing cough, tears and redness in eyes. It causes breathlessness and affects larynx. i.e, voice box.
2. SO2 dissolves in rain water and produces H2SO4 which demages building materials especially marble (CaCO3).
CaCO3 + H2SO3 → CaSO3 + H2O + CO2 ↓