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Which of the two: O2NCH2CH2O– or CH3CH2O– is expected to be more stable & why ?

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O2NCH2CH2O– is more stable than CH3CH2O– because NO2 group has –I effect and hence it tends to disperse the negative charge on the oxygen atom. In contrast, CH3CH2 has +I effect. It, therefore, tends to intensify the negative charge and hence destabilizes it.

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