Let centre of the hollow sphere(of radius r) is O and potential at centre is Vo.
Let point is P from where centre is at fistance 2r and potential at this point is Vp.
According to the question Vo-Vp=V
Now Vo =kq/r ,where q is the charge on hollow sphere.
VP=kq/2r
Vo-Vp=(kq/2r)=V q=(2rV/k)
Electric field at distance 3r from centre is kq/r²
Putting value of q here we get
E=2V/r This is the final answer.
I hope it helps