On mixing the clear solution of two ionic compounds, as a substance which is insoluble in water, is formed. This insoluble substance is known as a formed is called precipitation reaction.
Example: When sodium sulphate solution is mixed with barium chloride solution, a white precipitate of a substance (BaSO4) is formed.
Na2SO4(aq) +BaCl2(aq) → BaSO4↓ +2NaCl(aq)