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Discuss the manufacture of chlorine.

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Electrolytic process: 

When a solution of brine (NaCl) is electrolysed, Na+ and CP ions are formed. Na ion reacts with OH ions of water and forms sodium hydroxide. Hydrogen and chlorine are liberated as gases.

Deacons process: 

In this process a mixture of air and hydrochloric acid is passed up a chamber containing a number of shelves, pumice stones soaked in cuprous chloride are placed. Hot gases at about 723 K are passed through a jacket that surrounds the chamber.

The chlorine obtained by this method is dilute and is employed for the manufacture of bleaching powder. The catalysed reaction is given below,

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