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Explain Werner’s postulate using CO Cl3. 6NH3

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Explain Werner’s postulate using CO Cl3. 6NH3.

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Complex Groups satisfy the secondary valence (non- ionaisable, inner coordination sphere) No. of ionisable Cl ions in the complex (outer coordination sphere) No. of moles of AgCl formed = no. of moles of ionisable Cl-
COCl3.6NH3 6NH3 3Cl- 3 AgCl
COCl3.5NH3 5NH3 & 1Cl- 1Cl- 2 AgCl
COCl3.4NH3 4NH3 & 2Cl- 1Cl- 1 AgCl
COCl3.4NH3 4NH3 & 2Cl- 1Cl- 1 AgCl
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