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Indicate the types of isomerism exhibited by the following complexes and draw the structures for

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Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:

1. K[Cr(H2O) (C2O4)2] 

2. [CO(NH)3Cl]Cl2

3. K3 [Fe(CN)6] 

4. K3 [Fe(C2O4)3] 

5. K2[PdCl4] 

6. [Pt(NH3)2Cl(NH2CH3)]Cl

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1 Answer

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1. Both geometrical (cis, trans) and optical isomer for cis – form.

2. Two optical isomers can exist.

3. Linkage isomers [CO(NH3)5 ONO](NO3)2 and [CO(NH3) NO2](NO3)2

4. Geometrical isomerism.

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