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in Periodic Classification of Elements by (45.7k points)
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Justify that the fifth period of the periodic table should have 18 elements on the basis of quantum numbers.

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Fifth period of the periodic table have 18 elements. 5th period starts from Rb to Xe (18 elements). 5th period starts with principal quantum number n = 5 and 1 = 0, 1,2,3 and 4. When n = 5, the number of orbitals = 9. 

1 for 5s 

5 for 4d 

3 for 5p 

Total number of orbitals = 9. 

Total number of electrons that can be accommodated in 9 

orbitals = 9 x 2 = 18. 

Hence the number of elements in 5th period is 18.

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