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Explain about the periodic variation of electron gain enthalpy in a period and in a group.

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1. The electron gain enthalpy increases as we move from left to right in a period due to the increase of nuclear charge. However, Be, Mg, N and noble gases have almost zero value of electron gain enthalpy due to extra stability of completely and half filled orbitais. 

2. When we move in a group of periodic table, the size and nuclear charge increase. But the effect of increase in atomic size is much more pronounced than that of nuclear charge and thus the additional electron feels less attraction by the large atom. Consequently, electron gain enthalpy decreases.

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