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in Periodic Classification of Elements by (45.0k points)
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Give reasons: 

1. IE1 of sodium is lower than that of magnesium whereas IE2 of sodium is higher than that of magnesium. 

2. Noble gases have positive value of electron gain enthalpy

1 Answer

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1. The effective nuclear charge of magnesium is higher than that of sodium. For these reasons, the energy required to remove an electron from magnesium is more than the energy required in sodium. 

Hence, the first ionization enthalpy of sodium is lower than that of magnesium. 

2. Noble gases have completely filled electronic configuration and they are more stable. So in Noble gases addition of electron is not possible. Electron gain enthalpy is always the amount of energy released (-ve sign) when an electron is added to an atom. – Butin noble gases, if an electron is added, they have positive value of electron gain enthalpy.

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