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Explain how 2-butyne reacts with (a) Lindlar’s catalyst and (b) Sodium in liquid ammonia?

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(a) 2-butyne reacts with Lindlar’s catalyst: 

2-butyne can be reduced to cis-2 butene using CaCO3 supported in Pd -metal partially deactivated with sulphur. 

This reaction is stereo specific giving only the cis-2- butene.

(b) 2-butyne reacts with sodium in liquid ammonia: 

2-butyne can also be reduced to trans-2-butene using sodium in liquid ammonia. This reaction is stereospecific giving only the trans-2-butene.

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