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in Basic Concepts of Organic Reactions by (50.9k points)
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Which electron displacement effect explain the following correct orders of acidity of the carboxylic acids?

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CH3CH2COOH > (CH3)2 CHCOOH > (CH3)3 C COOH 

As the number of alkyl group increases, +I effect increases and it strengthen the O-H bond. i.e., O-H bond dissociation is very difficult.

Therefore +I effect explain the correct orders of acidity of the carboxylic acids.

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