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in Basic Concepts of Organic Reactions by (48.6k points)
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How does hyper conjugation effect explain the stability of alkenes?

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  • The relative stability of various classes of carhonium ions may be explained by the number of no bond resonance structures that can be written for them. 
  • Such structures are arrived by shifting the bonding electrons from an adjacent C-H bond to the electron deficient carbon. 
  • in this way, the positive charge originally on carbon is dispersed to the hydrogen. This manner of electron release by assuming no bond character in the adjacent C-H bond is called hyper conjugation or Baker- Nathan effect. 
  • The greater the hyper conjugation, the greater will be the stability of the compound. 

The increasing order of stability can be shown as:

  • Alkyl group increases in the C=C double bond carbon, hyper conjugation increases and stability of that organic compound also increases.

 

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