30% of benzene in carbon tetrachloride by mass means that Mass of benzene in the solution = 30g
Mass of solution = 100 g
Mass of carbon tetrachloride = 100g – 30g = 70g
Molar mass of benzene (C6H6) = 78 g mol-1
Molar mass of CCl4 = 12 + (4 x 35.5) = 154 g mol-1