Which of the following reactions involve homogeneous equilibrium or heterogeneous equilibrium?
(i) 2SO2 (g) + O2 (g) ⇌ 2SO3 (g)
(ii) C (s) + CO2 (g) ⇌ 2CO (g)
(iii) CH3COOC2H5 (aq) + H2O(1)
CH3COOH (aq) + C2H5OH (aq)
(iv) BaCO3 (s) ⇌ Bao (s) + CO2 (g)