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in Electrochemistry by (33.4k points)
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Every conductivity cell has a definite value for its cell constant.

1. What is cell constant? 

2. How is it related with specific conductance? 

3. Calculate the cell constant of a conductivity cell containing 0.05M KCl solution, whose resistance is 100 ohm and conductivity is 0.0075 ohm-1 cm-1

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1. The quantity ℓ/A is called cell constant.

A = Area of cross section of the electrodes.

ℓ = distance of separation of two electrodes.

2. Specific conductance = Cell constant × Conductance

3. Cell constant = Specific conductance × Resistance

= 0.0075 ohm 1 cm-1 × 100 ohm = 0.75 cm-1

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