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What is meant by the following terms? Give an example of the reaction in each case.

1. Cyanohydrin 

2. Acetal 

3. Semicarbazone 

4. Aldol 

5. Hemiacetal 

6. Oxime 

7. Ketal 

8. Imine 

9. 2,4-DNP-derivative 

10. Schi’s base

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1. Cyanohydrin – 

It is a compound which contain both OH and CN groups.

For example, Lactic acid can be obtained by hydrolysis of cyanohydrin.

2. Acetal – 

compounds formed by the reaction of aldehydes with monohydric alcohols in presence of dry HCI gas.

3. Semicarbazone –

the product of carbonyl compounds with semicarbazide is known as semicarbazone.

4. Aldol – 

It is a condensation product of aldehydes or ketones having at least one α – hydrogen atom with dilute alkali as catalyst.

5. Hemiacetal –

It is a compound which contains an ether as well as alcohol functional group.

For example, methoxyethanol is a hemiacetal.

6. Oxime –

Addition compound formed by the reaction of aldehyde or ketone with hydroxylamine.

7. Ketal – 

It is a cyclic compound obtained by reaction of aceone with ethylene glycol.

8. Imine – 

Addition compound formed by the reaction of aldehyde or ketone with ammonia.

9. 2, 4-DNP derivative –

2, 4-phenylhydrazone (DNP) is the addition compound formed by the reaction of aldehydes and ketones with 2, 4-dinitrophenylhydrazine.

10. Schiff’s base –

Addition compound formed by the reaction of aldehyde or ketone with amine.

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