(a) Chlorine when reacts with dry slaked lime bleaching powder is obtained.
Ca (OH)2 + Cl2 → Ca (OCl) Cl + H2O
(b) When chlorine reacts with hot and conc. Solution of NaOH, a mixture of sodium chloride and sodium chlorate is obtained.
6 NaOH + 3Cl2 → 5NaCl + NaClO3 + 3H2O