Answer is : (4) SiO2
In bauxite impurities of Fe2O3, TiO2 and SiO2 are present , Fe2O3 and TiO2 are basic oxides therefore does not reacts with or dissolve in NaOH whereas SiO2 is acidic oxide it gets dissolve in NaOH, hence leach out
SiO2 + 2NaOH → Na2SiO3(aq.) + H2O