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In order to prepare a 1° amine from an alkyl halide with simultaneous addition of one = CH2 group in the carbon chain, the reagent used as a source of nitrogen is

(a) potassium phthalimide, C6H4(CO)2 N-K+

(b) potassium cyanide, KCN

(c) sodium azide, NaN3

(d) sodium amide, NaNH2

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Correct option: (b) potassium cyanide, KCN

In order to prepare 1° amine from an alkyl halide with simultaneous addition of one = CH2 group in the carbon chain, the reagent used as a source of nitrogen is KCN. Chemical transformation can be shown as:

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