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in Chemistry by (74.1k points)
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Which molecule/ion out of the following does not contain unpaired electrons?
A. `N_(2)^(+)`
B. `O_(2)`
C. `O_(2)^(2-)`
D. `B_(2)`

1 Answer

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Best answer
Correct Answer - C
c) The electrons configuration of the given molecules, are
`N_(2)^(+)= sigma1s^(2), sigma^(star)1s^(2), sigma2s^(2), sigma^(star)2s^(2), pi2p_(x)^(2)=pip_(y)^(2), sigma2p_(z)^(1)`
It has one unpaired electron, `O_(2)= sigma1s^(2), sigma^(star)1s^(2), sigma2s^(2), sigma^(star)2s^(2), pi2p_(x)^(2)=pip_(y)^(2),pi^(star)2p_(x)^(1)~~pi^(star)2p_(y)^(1)`
`O_(2)` has two unpaired electrons.
`O_(2)^(-) = sigma1s^(2), sigma^(star)1s^(2), sigma2s^(2), sigma^(star)2s^(2), pi2p_(x)^(2)=pip_(y)^(2),pi^(star)2p_(x)^(2)~~pi^(star)2p_(y)^(2)`
Thus, `O_(2)^(2-)` has no unpaired electrons.
`B_(2) = sigma1s^(2), sigma^(star)1s^(2), sigma2s^(2), sigma^(star)2s^(2), pi2p_(x)^(1)=pip_(y)^(1)`
Thus, `B_(2)` has two unpaired electrons.

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