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Give reasons for the following:

(a) The size of the anion is greater than the size of the parent atom.

(b) argon atom is bigger than chlorine atom.

(c) Ionisation potential of the element increases across a period.

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(a) Anion is formed by the gain of electrons. Thus the numbers of electrons are more than protons. The effective positive charge in the nucleus is less, so less inward pull is experienced. Hence the size expands. So the size of an atom is greater than the size of parent atom.

(b) Since Argon has stable octet configuration, so due to the inter- electronic repulsions the effect of nuclear pull over the valence shell electrons cannot be seen which results in the bigger size.

(c) Since size of Bromine is bigger than chlorine, so it becomes more difficult for Br atoms to attract electrons. Thus, Cl is more reactive than Br.

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