The work is defined as the energy by which a body is displaced through a distance d by applying a force f.
∴ W = f × d
If area is A = d2 and volume V = d3 then,
PV = \(\frac{f}{A}\) x d3
= \(\frac{f}{d^2}\) x d3
= f × d = W
∴ The term PV represents the pressure-volume work.