(a) Freezing of a liquid results in decrease in randomness and disorder, hence entropy decreases, ΔS < 0.
(b) Sublimation of a solid converts it into vapour where the molecules or atoms are free to move randomly. Hence disorder increases accompanying increase in entropy, ΔS > 0.
(c) Dissolving sugar in water separates the molecules of sugar in the solution increasing disorder and entropy, ΔS > 0.
(d) Condensation of vapour decreases the disorder and randomness, hence entropy, ΔS < 0.
