(a) A boy is swimming in a pond: The work done is positive because the direction of applied force and displacement are the same.
(b) A coolie is standing with a load on his head: The work done is zero because the applied force does not cause any displacement.
(c) Stopping a moving car by applying brakes: The work done is negative because the fore applied by the brakes acts in a direction opposite to the direction of motion of car.
(d) Catching the ball which you friend has thrown towards you : Negative work because the force required to stop the ball, acts opposite to the displacement of the ball.