Step 1:
Rewrite the given equation as it is
KCN + H2SO4 → K2SO4 + HCN
Step 2:
Write the number of atoms of each element or group in the unbalanced equation on both sides of the equation.
Element |
Number of atoms in reactants |
Number of atoms in products |
K |
1 |
2 |
CN (group) |
1 |
1 |
O |
4 |
4 |
H |
4 |
4 |
S |
1 |
1 |
The number of oxygen atoms involved in different compounds on both sides (reactants and products) are equal. Therefore, balance the number of atoms of the second element, potassium.
Step 3:
To balance K atoms:
Number of atoms of Potassium |
In reactants |
In products |
To begin with |
2 (KCN) |
2 (in K2SO4) |
To balance |
1 × 2 |
2 |
To equalise the number of potassium atoms, we use 2 as the coefficient of KCN in the reactants.
Now, the partly balanced equation becomes
2KCN + H2SO4 → K2SO4 + 2HCN
Now, count the atoms of each element on both sides of the equation. The number of atoms on both sides are equal. Hence, the balanced equation is
2KCN + H2SO4 → KgSO4 + 2HCN
Now indicate the physical states of the reactants and the products.
2KCN(aq) + H2SO4(aq) → K2SO4(aq) + 2HCN(g)