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Explain by giving equation for the reaction :
(i) `Mn^(3+)` disproportionates to `Mn^(2+)` and `MnO_(2)` in acidic medium.
(ii) `KMnO_(4)` heated with KOH

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(i) `2Mn^(+3) +2H_(2)O to Mn^(+2) +MnO_(2) +4H^(+)`
(ii) ` 4KMnO_(4)+4KOH to 4K_(2)MnO_(4)+2H_(2)O+2H_(2)O+O_(2)`

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