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State the different characteristic features of nanoparticles.

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The nanoparticle science is special as at such a small scale, different laws dominate than what we experience in our everyday life.

The characteristic features like optical properties, catalytical activities, have huge surface area and good thermal properties mechanical strength electrical conductivity vary than that of bulk material.

(1) Colour : At nanoscale this optical property behaves differently. Elemental gold has nice shining yellow colour, but nanoparticles of gold show red colour.

(2) Catalytic activity : Since the surface area of nanoparticles is large they show increased catalytic activity. They are usually heterogenous catalyst that means catalysts are solid form and the reactions occur on the surface of the catalyst. These catalysts can be easily separated and recycled. 

For example : Pd, Pt metal nanoparticles used in hydrogenation reactions. Ti02, ZnO are used in photocatalysis. Gold in bulk is unreactive but the nanoparticles of gold behave as very good catalyst for organic reactions.

(3) Surface area : High surface-to-volume ratio is a very important characteristic of nanoparticles. Bulk material if subdivided into a group of individual nanoparticles, the total volume remains the same, but the collective surface area is largely increased. With large surface area for the same volume, these small particles react much faster because more surface area provides more number of reaction sites, leading to more chemical reactivity. Explanation of increase in surface area with decrease in particle size.

(4) Thermal strength : The melting point of nanomaterial changes drastically with size.

For example : Sodium clusters (Nan) of 1000 atoms melts at 288 K, 10000 atoms melt at 303 K and bulk sodium melts at 371 K.

(5) Mechanical strength : The mechanic al strength of nano clusters increase the hardness of the metal.

For example : nanoparticles of copper and palladium clusters with diameter in the range of 5-7 nm have hardness up to 500 r. greater than the bulk metal.

(6) Electrical conductivity : At nanoscale level the electrical conductivity changes. 

For example : Carbon nanotubes behave as a conductor or semiconductor whereas carbon is nonconductor.

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