Correct Answer - C
We know that the value of collgative property is directly proportional to no. of particles of solute .Since`K_(4)[Fe(CN)_(6)]`and `Al_(2)(SO_(4))_(3)`both from `5` ion on dissociation .Hence osmotic pressure of `Al_(2)(SO_(4))_(3)`solution will be nearest to that of equimolar solution of `K_(4)[Fe(CN)_(6)]`