Solubility of NaCI =6.15 mol/litre

(a) Thus amount of NaCl in 100 mL at 20°C get dissolved = 36 g and amount of NaCl in 100 mL at 20°C remained undissolved = 100-36 = 64 g
(b) If volume of solution is diluted to 200 mL, 36 g more of NaCl will be dissolved leaving only 28 g NaCl dissolved in 200 mL.