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Which of the following pairs represents linkage isomers ? (a) [Cu(NH3)4][PtCl4] and [Pt(NH3)4][CuCl4]

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Which of the following pairs represents linkage isomers ?
(a) [Cu(NH3)4][PtCl4] and [Pt(NH3)4][CuCl4]
(b) [Pd(PPh3)2(NCS)2] and [Pd(PPh3)2(SCN)2]
(c) [Co(NH3)5(NO3)]SO4 and [Co(NH3)5(SO4)]NO3
(d) [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2

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1 Answer

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Correct option (b) [Pd(PPh3)2(NCS)2] and [Pd(PPh3)2(SCN)2]

Explanation:

Linkage isomers are caused due to the presence of ambidentate ligands [Pd(PPh3)2(NCS)2] and [Pd(PPh3)2(SCN)2] are linkage isomers due to SCN, an ambidentate ligand.

Thus, SCN can linked to Pd by both N as well as S through their tone pairs.

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