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The correct order of electron gain enthalpy with negative sign of F, Cl, Br and I, having atomic numb er 9, 17 ,35 and 53 respectively, is

(a)I>Br>Cl>F (b)F>Cl>Br>I (c)Cl>F>Br>I (d)Br>Cl>I>F

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Correct Option(c)Cl>F>Br>I

Explanation:

As we go down the group in periodic table, atomic size increases, force of attraction for the added electron decreases. Thus, the added electron becomes loosely bound. Hence, electron gain enthalpy decreases down a group.

The fact that fluorine has a less electron gain enthalpy than chlorine seems to be due to the relatively greater the effectiveness of 2p-electron in the small F-atom to repel the additional electron entering the atom than 3p-electrons in the larger Cl-atom.

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