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दिया है , `E_(Cr^(3+)//Cr)^(@)=-0.72V, E_(Fe^(2+)//Fe)=-0.42V` सैल `Cr//Cr^(3+)(0.1M)||Fe^(2+)(0.01M)|Fe` के लिए विभव है -
A. `0.26V`
B. `0.339V`
C. `-0.339 V`
D. `-0.26 V`.

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Best answer
Correct Answer - A
`E_("सैल")=E_(R)^(@)-E_(L)^(@)=E_(Fe^(2+)//Fe)^(@)-E_(Cr^(3+)//Cr)^(@)`
`=-0.42-(-0.72)=0.3V`
दी गयी सैल की सैल अभिक्रिया निम्न है - `2Cr(s)+3Fe^(2+)(aq)to2Cr^(3+)(aq)+3Fe(s)` तथा `n=6`.
`E_("सैल")=E_("सैल")-(0.059)/(n)log_(10).([Cr^(3+)]^2)/([Fe^(2+)]^3)`
`=0.3-(0.059)/(6)log_(10).((0.1)^2)/((0.01)^3)=0.3-0.039`
`=0.261V`.

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