(i) The triple point of water has been assigned a fixed value of 273.15 K. This number represents a unique value associated with a unique condition of temperature and pressure in which all the three phases of water co-exist. On the other hand, melting point of ice and boiling point of water do not have a unique set of values as they are subject to changes in pressure and volume. For this reason, triple point of water is a standard fixed point in modem thermometry.
(ii) On Celsius scale, the melting point of ice at normal pressure has a value 0 °C. The value corresponding to this value on the absolute scale is 273.15 K. The value 273.16 K denotes the triple point of water which has a value, 273.16 – 273.15 = 0.01 °C on Celsius scale as per the given relation.
