Correct Answer - Option 4 : Shirt and Tailor
Here, except 'Shirt and Tailor' all other options belong to different groups. Tea and coffee are both beverage crops, Cycle and scooter are both two wheels mode of transportation, Rifle and Sword both are weapons used in fights but Shirt and Tailor is odd here as Tailor is the person who makes shirt with his skills.
Hence, "Shirt and Tailor" is the odd one here.