Correct option (a) Mg2+
Explanation:
The electronic configuration of the given ions are as follows.
12Mg2+ = 1s2 , 2s2 2p6 (No unpaired electron)
22Ti3+ = 1s2 , 2s2 2p6,3s23p63d1
(One unpaired electron)
23V3+ = 1s2 , 2s2 2p6,3s23p63d2 (Two unpaired elcctrons)
26Fe2+ = 1s2 , 2s2 2p6,3s23p63d6 (Four unpaired electrons)