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Some reactions of NO2 relevant to photochemical smog formation are

Identify A, B, X and Y 

(1) X = [O], Y = NO, A = O2, B = O3

(2) X = N2O, Y = [O], A = O3, B = NO

(3) X = 1/2 O2, Y = NO2, A = O3, B = O2

(4) X = NO, Y = [O], A = O2, B = N2O3

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