(a) We shall neglect the effects of the electrons outside the nucleus and consider only the motion of the µ in the Coulomb field of the Al nucleus. The energy levels of µ in a hydrogen-like atom of nuclear charge 2 (in the nonrelativistic approximation) are given by

(b) To take into account the motion of the nucleus, we simply have to replace the mass m of the meson with its reduced mass \(\mu = \frac{Mm}{M + m}\), M being the nuclear mass. Thus

(c) Taking into account the relativistic effects the muon kinetic energy is

The relativistic correction introduces a perturbation Hamiltonian

The energy correction AE for E1 is then

(d) In the scattering of neutrons by a nucleus, an attractive strong nuclear force sets in when the distance becomes smaller than \(r\sim r_0A^{\frac 13}\), where \(r_0\sim 1.2 \times 10^{-13}\) and A is the atomic mass number of the nucleus. r is generally taken to be the radius of the nuclues, which for Al is

The difference between the radius of the nucleus of Al and that of the first orbit of the µ-mesic atom is not very large, so that there is a considerable overlap of the wave functions of the nucleus and the muon. This effect, due to the finite volume of the nucleus, will give rise to a positive energy correction. At the same time there's also a large interaction between the muon and the magnetic moment of the nucleus.
Under similar circumstances, for the π-mesic atom there is also the volume effect, but no interaction with the magnetic moment of the nucleus as p-ions have zero spin.