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A metal forms sulphate isomorphous with white vitriol. If its equivalent weight is 29.4, determine the atomic weight of the metal.

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As the metal sulphate is isomorphous with white vitriol (ZnSO4.7H2O), its formula is MSO4.7H2O. 

Therefore, valency of the metal = 2.

At. wt.= Eq. wt. x Valency

= 29.4 x 2

= 58.8

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