The relevant balanced chemical equation is
\(\underset{\;\\1 \text{mole}\\2 \times 127\\=254g}{I_2} + \underset{\;\\2\text{moles}\\2(2\times 35.5)\\= 142 g}{2Cl_2} \longrightarrow \underset{\;\\1\text{mole}}{ICl} + \underset{\;\\1\text{mole}}{ICl_3}\)
According to equation, 254 g of I2 form = 1 mole of ICl
25.4 g of 12 form = \(\frac1{254}\) x 25.4 mole of ICI = 0.1 mole of ICI
Similarly, 254 g of I2 form = 1 mole of ICl3
1 25.4 g of I2 form = \(\frac1{254}\) x 25.4 mole of ICl3 = 0.1 mole of ICl3