Let r = distance of each charge at vertex from the center of cube.

Potential at the centre O = Potential due to each of 8 charges
= \(\frac{1}{4\piɛ_o}. \frac{8q}{r}\)

∴ Potential at O, V = \(\frac{1}{4\piɛ_o}\ \times\ \frac{8q\times2}{\sqrt3b}\)
= \(\frac{4q}{\sqrt3\piɛ_ob}\)
However, electric field inside a symmetrically shaped surface is zero since fields will mutually cancel each other.