Given, T = 27+ 273 = 300 K; V = 2.0 L
R = 0.0821 L atm K-1mol-1
Number of moles of NO2
\( = \frac{10^{23}}{6.022\times 10^{23}}\)
0.166 mol
From ideal gas equation,
PV = nRT
\(P = \frac{nRT}{V}\)
\( = \frac{0.166\ mol\times 0.0821\ L\ atm\ K^{-1}\ mol^{-1}\times 300\ K}{2.0\ L}\)
= 0.204 atm
So, pressure in container = 0.205 atm.